PittsburghV1, Main, Exploration, bibRecord, 007B55

N‐Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition

Identifieur interne : 007B55 ( Main/Exploration ); précédent : 007B54; suivant : 007B56

N‐Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition

Auteurs : Jacques Lalevée [France] ; Sofia Telitel [France] ; Mohamad Ali Tehfe [France] ; Jean Pierre Fouassier [France] ; Dennis P. Curran [États-Unis] ; Emmanuel Lacôte [France]

Source :

Angewandte Chemie [ 0044-8249 ] ; 2012-06-11.

RBID : ISTEX:564305BB03165ADA09A04F7D9B7A460B8848173A

English descriptors

Abstract

Starthilfe: Die Effizienz von Typ‐I‐Photoinitiatoren in der radikalischen Acrylatpolymerisation wird durch den Zusatz von NHC‐Boranen deutlich erhöht. Ein Wasserstoffatomtransfer auf die zunächst gebildeten Radikale R. (siehe Schema) erzeugt stark nucleophile NHC‐Boryl‐Radikale, die besser für den anschließenden Initiationsprozess durch Reaktion mit dem Monomer geeignet sind.

Url:

https://api.istex.fr/document/564305BB03165ADA09A04F7D9B7A460B8848173A/fulltext/pdf

DOI: 10.1002/ange.201200975

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 001406
to stream Istex, to step Curation: 001406
to stream Istex, to step Checkpoint: 001504
to stream Main, to step Merge: 008033
to stream Main, to step Curation: 007B55

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">N‐Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition</title>
<author><name sortKey="Lalevee, Jacques" sort="Lalevee, Jacques" uniqKey="Lalevee J" first="Jacques" last="Lalevée">Jacques Lalevée</name>
</author>
<author><name sortKey="Telitel, Sofia" sort="Telitel, Sofia" uniqKey="Telitel S" first="Sofia" last="Telitel">Sofia Telitel</name>
</author>
<author><name sortKey="Tehfe, Mohamad Ali" sort="Tehfe, Mohamad Ali" uniqKey="Tehfe M" first="Mohamad Ali" last="Tehfe">Mohamad Ali Tehfe</name>
</author>
<author><name sortKey="Fouassier, Jean Pierre" sort="Fouassier, Jean Pierre" uniqKey="Fouassier J" first="Jean Pierre" last="Fouassier">Jean Pierre Fouassier</name>
</author>
<author><name sortKey="Curran, Dennis P" sort="Curran, Dennis P" uniqKey="Curran D" first="Dennis P." last="Curran">Dennis P. Curran</name>
</author>
<author><name sortKey="Lacote, Emmanuel" sort="Lacote, Emmanuel" uniqKey="Lacote E" first="Emmanuel" last="Lacôte">Emmanuel Lacôte</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:564305BB03165ADA09A04F7D9B7A460B8848173A</idno>
<date when="2012" year="2012">2012</date>
<idno type="doi">10.1002/ange.201200975</idno>
<idno type="url">https://api.istex.fr/document/564305BB03165ADA09A04F7D9B7A460B8848173A/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">001406</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001406</idno>
<idno type="wicri:Area/Istex/Curation">001406</idno>
<idno type="wicri:Area/Istex/Checkpoint">001504</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">001504</idno>
<idno type="wicri:doubleKey">0044-8249:2012:Lalevee J:n:heterocyclic:carbene</idno>
<idno type="wicri:Area/Main/Merge">008033</idno>
<idno type="wicri:Area/Main/Curation">007B55</idno>
<idno type="wicri:Area/Main/Exploration">007B55</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">N‐Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition<ref type="note" target="#nss"></ref>
</title>
<author><name sortKey="Lalevee, Jacques" sort="Lalevee, Jacques" uniqKey="Lalevee J" first="Jacques" last="Lalevée">Jacques Lalevée</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>IS2M (LRC CNRS 7228), ENSCMu‐UHA, 15 rue Jean Starcky</wicri:regionArea>
<wicri:noRegion>15 rue Jean Starcky</wicri:noRegion>
<wicri:noRegion>15 rue Jean Starcky</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">France</country>
</affiliation>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>Jacques Lalevée, IS2M (LRC CNRS 7228), ENSCMu‐UHA, 15 rue Jean Starcky, 68057 Mulhouse Cedex (France)Emmanuel Lacôte, ICSN CNRS, Av. de la Terrasse</wicri:regionArea>
<wicri:noRegion>Av. de la Terrasse</wicri:noRegion>
<wicri:noRegion>Av. de la Terrasse</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Telitel, Sofia" sort="Telitel, Sofia" uniqKey="Telitel S" first="Sofia" last="Telitel">Sofia Telitel</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>IS2M (LRC CNRS 7228), ENSCMu‐UHA, 15 rue Jean Starcky</wicri:regionArea>
<wicri:noRegion>15 rue Jean Starcky</wicri:noRegion>
<wicri:noRegion>15 rue Jean Starcky</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Tehfe, Mohamad Ali" sort="Tehfe, Mohamad Ali" uniqKey="Tehfe M" first="Mohamad Ali" last="Tehfe">Mohamad Ali Tehfe</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>IS2M (LRC CNRS 7228), ENSCMu‐UHA, 15 rue Jean Starcky</wicri:regionArea>
<wicri:noRegion>15 rue Jean Starcky</wicri:noRegion>
<wicri:noRegion>15 rue Jean Starcky</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Fouassier, Jean Pierre" sort="Fouassier, Jean Pierre" uniqKey="Fouassier J" first="Jean Pierre" last="Fouassier">Jean Pierre Fouassier</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>ENSCMu‐UHA, 3 rue Alfred Werner</wicri:regionArea>
<wicri:noRegion>3 rue Alfred Werner</wicri:noRegion>
<wicri:noRegion>3 rue Alfred Werner</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Curran, Dennis P" sort="Curran, Dennis P" uniqKey="Curran D" first="Dennis P." last="Curran">Dennis P. Curran</name>
<affiliation wicri:level="4"><country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Chemistry, University of Pittsburgh, Pittsburgh</wicri:regionArea>
<placeName><settlement type="city">Pittsburgh</settlement>
<region type="state">Pennsylvanie</region>
<settlement type="city">Pittsburgh</settlement>
</placeName>
<orgName type="university">Université de Pittsburgh</orgName>
</affiliation>
</author>
<author><name sortKey="Lacote, Emmanuel" sort="Lacote, Emmanuel" uniqKey="Lacote E" first="Emmanuel" last="Lacôte">Emmanuel Lacôte</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>ICSN CNRS, Av. de la Terrasse</wicri:regionArea>
<wicri:noRegion>Av. de la Terrasse</wicri:noRegion>
<wicri:noRegion>Av. de la Terrasse</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">France</country>
</affiliation>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>Jacques Lalevée, IS2M (LRC CNRS 7228), ENSCMu‐UHA, 15 rue Jean Starcky, 68057 Mulhouse Cedex (France)Emmanuel Lacôte, ICSN CNRS, Av. de la Terrasse</wicri:regionArea>
<wicri:noRegion>Av. de la Terrasse</wicri:noRegion>
<wicri:noRegion>Av. de la Terrasse</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">Angewandte Chemie</title>
<title level="j" type="alt">ANGEWANDTE CHEMIE</title>
<idno type="ISSN">0044-8249</idno>
<idno type="eISSN">1521-3757</idno>
<imprint><biblScope unit="vol">124</biblScope>
<biblScope unit="issue">24</biblScope>
<biblScope unit="page" from="6060">6060</biblScope>
<biblScope unit="page" to="6063">6063</biblScope>
<biblScope unit="page-count">4</biblScope>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2012-06-11">2012-06-11</date>
</imprint>
<idno type="ISSN">0044-8249</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0044-8249</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Abstract hydrogen atoms</term>
<term>Acrylate</term>
<term>Angew</term>
<term>Boryl radicals</term>
<term>Chem</term>
<term>Curran</term>
<term>Fouassier</term>
<term>Hydrogen atom</term>
<term>Light irradiation</term>
<term>Makhlouf brahmi</term>
<term>Methyl acrylate</term>
<term>Oxygen inhibition</term>
<term>Phenylthiyl radicals</term>
<term>Photoinitiators</term>
<term>Photopolymerization</term>
<term>Photopolymerization reaction</term>
<term>Polymer chains</term>
<term>Polymerization</term>
<term>Polymerization profiles</term>
<term>Room temperature</term>
<term>Thiyl radicals</term>
<term>Unproductive peroxyl radicals</term>
<term>Verlag gmbh</term>
<term>Weinheim angew</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Abstract hydrogen atoms</term>
<term>Acrylate</term>
<term>Angew</term>
<term>Boryl radicals</term>
<term>Chem</term>
<term>Curran</term>
<term>Fouassier</term>
<term>Hydrogen atom</term>
<term>Light irradiation</term>
<term>Makhlouf brahmi</term>
<term>Methyl acrylate</term>
<term>Oxygen inhibition</term>
<term>Phenylthiyl radicals</term>
<term>Photoinitiators</term>
<term>Photopolymerization</term>
<term>Photopolymerization reaction</term>
<term>Polymer chains</term>
<term>Polymerization</term>
<term>Polymerization profiles</term>
<term>Room temperature</term>
<term>Thiyl radicals</term>
<term>Unproductive peroxyl radicals</term>
<term>Verlag gmbh</term>
<term>Weinheim angew</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract">Starthilfe: Die Effizienz von Typ‐I‐Photoinitiatoren in der radikalischen Acrylatpolymerisation wird durch den Zusatz von NHC‐Boranen deutlich erhöht. Ein Wasserstoffatomtransfer auf die zunächst gebildeten Radikale R. (siehe Schema) erzeugt stark nucleophile NHC‐Boryl‐Radikale, die besser für den anschließenden Initiationsprozess durch Reaktion mit dem Monomer geeignet sind.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>États-Unis</li>
</country>
<region><li>Pennsylvanie</li>
</region>
<settlement><li>Pittsburgh</li>
</settlement>
<orgName><li>Université de Pittsburgh</li>
</orgName>
</list>
<tree><country name="France"><noRegion><name sortKey="Lalevee, Jacques" sort="Lalevee, Jacques" uniqKey="Lalevee J" first="Jacques" last="Lalevée">Jacques Lalevée</name>
</noRegion>
<name sortKey="Fouassier, Jean Pierre" sort="Fouassier, Jean Pierre" uniqKey="Fouassier J" first="Jean Pierre" last="Fouassier">Jean Pierre Fouassier</name>
<name sortKey="Lacote, Emmanuel" sort="Lacote, Emmanuel" uniqKey="Lacote E" first="Emmanuel" last="Lacôte">Emmanuel Lacôte</name>
<name sortKey="Lacote, Emmanuel" sort="Lacote, Emmanuel" uniqKey="Lacote E" first="Emmanuel" last="Lacôte">Emmanuel Lacôte</name>
<name sortKey="Lacote, Emmanuel" sort="Lacote, Emmanuel" uniqKey="Lacote E" first="Emmanuel" last="Lacôte">Emmanuel Lacôte</name>
<name sortKey="Lalevee, Jacques" sort="Lalevee, Jacques" uniqKey="Lalevee J" first="Jacques" last="Lalevée">Jacques Lalevée</name>
<name sortKey="Lalevee, Jacques" sort="Lalevee, Jacques" uniqKey="Lalevee J" first="Jacques" last="Lalevée">Jacques Lalevée</name>
<name sortKey="Tehfe, Mohamad Ali" sort="Tehfe, Mohamad Ali" uniqKey="Tehfe M" first="Mohamad Ali" last="Tehfe">Mohamad Ali Tehfe</name>
<name sortKey="Telitel, Sofia" sort="Telitel, Sofia" uniqKey="Telitel S" first="Sofia" last="Telitel">Sofia Telitel</name>
</country>
<country name="États-Unis"><region name="Pennsylvanie"><name sortKey="Curran, Dennis P" sort="Curran, Dennis P" uniqKey="Curran D" first="Dennis P." last="Curran">Dennis P. Curran</name>
</region>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Amérique/explor/PittsburghV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 007B55 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 007B55 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Amérique
   |area=    PittsburghV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:564305BB03165ADA09A04F7D9B7A460B8848173A
   |texte=   N‐Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition
}}

This area was generated with Dilib version V0.6.38.
Data generation: Fri Jun 18 17:37:45 2021. Site generation: Fri Jun 18 18:15:47 2021

	Serveur d'exploration sur Pittsburgh
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur Pittsburgh

N‐Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition

N‐Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri